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    自1991年Arduengo小組成功分離出游離的N-雜環卡賓(NHC)化合物后,NHC的合成、反應性能等受到化學界的高度關注。NHC及其金屬化合物穩定性高,且富含電子,因而成為烯烴復分解反應和C-C偶聯反應的研究熱點。百靈威可提供一系列NHC配體及金屬化合物。

    ■NHC化合物

    產品編號
    英文名稱
    CAS
    規格
    價格
    結構式
    1,3-Bis(1-adamantyl)imidazoliumchloride,
    min.97%
    250mg

     
    ¥1440
     
    1,3-Bis(1-adamantyl)imidazol-2-ylidene,
    min.98%ARDUENGO'SCARBENE
    250mg

     
    ¥2175
     
    1,3-Bis(t-butyl)imidazoliumtetrafluoroborate,
    min.97%ItBuHBF4
    250mg
    2g
    ¥1020
    ¥3060
     
    1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol
    -2-ylidine,min.98%
    250mg
    2g
    ¥1440
    ¥4020
     
    1,3-Bis(2,6-di-i-propylphenyl)imidazolium
    chloride, min. 97%
    250mg
    2g
    ¥990¥2970
     
    1,3-Bis(2,6-di-i-propylphenyl)-4,5-
    dihydroimidazoliumtetrafluoroborate,min.95%
    1g
    5g
     
    ¥1050
    ¥4200
     
    2,3-Bis(2,6-di-i-propylphenylimino)butane,98%
    500mg
    2g
    ¥720
    ¥2160
     
    1,3-Bis(2,4,6-trimethylphenyl)-4,5-
    dihydroimidazoliumtetrafluoroborate,min.95%
    1g
    5g
    ¥840
    ¥3360
     
    1,3-Bis(2,4,6-trimethylphenyl)imidazoliumchloride,
    min.97%
    1g
    5g
    ¥690
    ¥2760
     
    1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene,
    min.98%
    500mg
    2g
    ¥1170
    ¥3210
     
    1,3-Di-t-butylimidazoliumchloride,min.98%
    250mg
    ¥750
     
    1,3-Di-t-butylimidazol-2-ylidene,min.98%
    250mg
    ¥1500
     
    1,3-Di-i-propylimidazoliumchloride,min.97%
    1g
    5g
    ¥525
    ¥2100
     
    1,3-Bis(4-chlorophenyl)imidazoliumchloride,
    min.97%
    250mg
    ¥825
     

    ■ Pd-NHC化合物

    產品編號
    英文名稱
    CAS
    規格
    價格
    結構式
    Allylchloro[1,3-bis(2,6-di-i-propylphenyl)-4,5-
    dihydroimidazol-2-ylidene]palladium(II),97%
    250mg
    1g
    ¥1260
    ¥3780
     
    Allylchloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-
    2-ylidene]palladium(II),98%
    250mg
    1g
    ¥1260
    ¥3780
     
    Allylchloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-
    2-ylidene]palladium(II),98%
    250mg
    1g
    ¥1260
    ¥3780
     
    Chloro[(1,2,3-n)-3-phenyl-2-propenyl][1,3-bis(2,6-
    di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]p
    alladium(II),min.97%
    250mg
    1g
    ¥1080
    ¥3240
     
    Chloro[(1,2,3-?)-3-phenyl-2-propenyl][1,3-bis(2,6-
    di-i-propylphenyl)imidazol-2-ylidene]palladium(II),
    min.97%
    250mg
    1g
    ¥1080
    ¥3240
     
    cis-Dichloro(N,N,N',N'-tetramethylethylenediamin
    e)palladium(II),99%
    250mg
    1g
    ¥375
    ¥1110
     
    cis-Dimethyl(N,N,N',N'-tetramethylethylenediamin
    e)palladium(II),99%
    250mg
    1g
    ¥1125
    ¥3375
     

    ■ 其他N雜環化合物

    產品編號
    英文名稱
    CAS
    規格
    價格
    結構式
    11,12-Bis[N-benzyl-1H-imidazolium-3-methylene
    ]-9,10-dihydro-9,10-ethanoanthracenebis
    (trifluoromethanesulfonate)
    N/A
    100mg
    500mg
    ¥1080
    ¥4320
     
    (1R,2R)-(+)-1,2-Bis(4-cyanophenyl)
    ethylenediaminedihydrochloride,min.98%
    100mg
    500mg
    ¥1020
    ¥4080
     
    11,12-Bis[1,3-dihydro-3-(i-propyl)-2H-benzimidazol
    -2-ylidene-3-methylene]-9,10-dihydro-9,10
    -ethanoanthracene
    100mg
    500mg
    ¥1080
    ¥4320
     
    11,12-Bis[N-(2,2-diphenyl-1-ethyl)-1H-benzimidazolium-
    3-methylene]-9,10-dihydro-9,10-ethanoanthracenebis
    (trifluoromethanesulfonate)
    N/A
    100mg
    500mg
    ¥1080
    ¥4320
     
    2,3-Bis(2,6-di-i-propylphenylimino)butane,98%
    500mg
    2g
    ¥720
    ¥2160
     
    N,N'-Bis(2-hydroxybenzyl)ethylenediamine,
    min.98%H4SALEN
    5g
    25g
    ¥915
    ¥3525
     
    11,12-Bis[N-methyl-1H-benzimidazolium-3-methylene]-
    9,10-dihydro-9,10-ethanoanthracenebis
    (trifluoromethanesulfonate)
    100mg
    500mg
    ¥1080
    ¥4230
     
    11,12-Bis[N-(2-methylbenzyl)-1H-benzimidazolium-3-
    methylene]-9,10-dihydro-9,10-ethanoanthracenebis
    (trifluoromethanesulfonate)
    N/A
    100mg
    500mg
    ¥1080
    ¥4320
     
    11,12-Bis[N-(i-propyl)-1H-benzimidazolium-3-methylene]-
    9,10-dihydro-9,10-ethanoanthracenebis
    (trifluoromethanesulfonate)
    100mg
    500mg
    ¥1080
    ¥4320
     
    11,12-Bis[3-methylimidazolium]-9,10-dihydro-
    9,10-ethanoanthracenebis(iodide)
    N/A
    100mg
    500mg
    ¥2445
    ¥9780
     
    (4S)-(-)-2-(4-t-Butyl-4,5-dihydro-oxazol-2-yl)propan-2-ol,
    98%
    N/A
    250mg
    1g
    ¥1050
    ¥3150
     
    (5aR,10bS)-(+)-5a,10b-Dihydro-2-(pentafluorophenyl)-
    4H,6H-indeno[2,1-b][1,2,4]trizolo[4,3-d][1,4]
    oxaziniumtetrafluoroborate,min.98%
    250mg
    1g
    ¥1170
    ¥3510
     
    (5aS,10bR)-(-)-5a,10b-Dihydro-2-(pentafluorophenyl)-
    4H,6H-indeno[2,1-b][1,2,4]trizolo[4,3-d][1,4]
    oxaziniumtetrafluoroborate,min.98%
    100mg
    500mg
    ¥825
    ¥3300
     
    6,7-Dihydro-2-pentafluorophenyl-5H-pyrrolo
    [2,1-c]-1,2,4-triazoliumtetrafluoroborate,min.98%
    N/A
    250mg
    1g
    ¥1170
    ¥3510
     
    6,7-Dihydro-2-phenyl-5H-pyrrolo[2,1-c]-1,2,4-
    triazoliumchloride,min.98%
    250mg
    1g
    ¥900
    ¥2700
     

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